Anti- Epileptic drugs & Anti - parkinsonism drugs

Sunday, October 10, 2010


Def-  It is a collective term applied for a group of convulsive disorders

The common features of epilepsy are

Loss or disturbance of consciousnesses
Characteristic body movements (usually, but not always)

CLASSIFICATION

1. Hydantoins
Phenytoin

2. Barbiturates
Phenobarbitone
Primidone

3. Iminostilbbenes
Carbamazepine

4. Succinimides
Ethosuximide

5. Aliphatic carboxylic acid
Sodium valproate

6. Benzodiazepines
Clonazepam
Clobazam
Diazepam

7. Newer antiepileptic
Lamotrigine
Gbapentine

8. Miscellaneous
Trimethadione
Acetazolamide

1. Phenytoin

Phenytoin was synthesized in 1908, but its anticonvulsant property was discovered only in 1938
It is effective in suppressing tonic-clinic and partial seizures and  is a drug of choice for initial therapy, particularly in treating adults
Mechanism of action
Antiepileptic drugs are believed to suppress the formation or spread of abnormal electrical discharges in the brain
 There are different mechanisms
  1. Inhibition of t he sodium or calcium influx responsible for neuronal depolarization
  2. Augmentation of inhibitory GABA neurotransmission
  3. Inhibition of excitatory glutamate neurotransmission

1. Effect on ion channels
Under normal circumstances, voltage- sensitive ( voltage gated) sodium channels are rapidly opened when t he neuronal membrane potential (voltage) reaches its threshold

This causes rapid depolarization of the membrane and the conduction of an action potential along the neuronal axon

When action potential reaches the nerve terminal . it evokes the release of a neurotransmitter

After the neuronal membrane is depolarized, the sodium channels is inactivated by closure of the channels inactivation gate

The inactivation gate must be opened before the next action potential can occur

Many antiepileptic drugs , including carbamazepine, lamotrigine, phenytoin and topiramate  prologs the time that the sodium channels inactivation gate remains closed and this delays the formation of the next action  potential

These drugs bind to the channel when it is opened a greater percentage of the time than are slowly firing neurons, the drugs exhibit use dependent blockade

For this reason , the drugs suppress abnormal repetitive depolarization in a seizure focus more than they suppress normal  activity

By these action, carbamazepine and other drugs prevent the spread of abnormal discharges in a seizure focus to other neurons

A few drugs ( Ex – ethosuximide and valproate) block T- type ( low- threshold ) calcium channels that are located in thalamic neurons and participate in the initiation of generalized absence seizures
 2. GABA ergic systems

Antiepileptic drugs facilitate GABA neurotransmission by various means

Benzodiazepines (eg- clonazepam ) and barbiturates ( eg – Phenobarbital ) enhance GABA activation of the GABA A , receptor- chloride ion channel

Topiramate is believed to enhance activation of the GANA A receptor, Ganapentin increases GABA release , whereas valproate inhibits GABA degradation

Drugs that augment GANA may serve to counteract the excessive excitatory neurotransmission responsible for initiation and spreading abnormal electrical discharges

3. Effects on glutaminergic systems

A few antiepileptic drugs, including felbamate, topiramate and valproate , inhibit glutamate neurotransmission and other drugs that work via this mechanism are under development

This is an attractive mechanism of action because it may affect the formation of a seizure focus and thereby terminate a seizure at an early stage of its development

Seizure is caused by the synchronous discharge of a group of neurons in the cortex

Activation of N- methyl-D- aspartate (NMDA) receptors increases calcium influx and nitric oxides synthesis

NO then diffuses to presynpatic neuron and increases the release of glutamate via formation of cyclic guanosine monophosphate

Increased excitatory glutamate neurotransmission leads to long term potentiation

Long term potentiation is believed to facilitate a depolarization shift , characterized by prolonged depolarization s with spikelets

The depolarization shift can cause adjacent neurons to discharge synchronously and thereby precipitate a seizure

 Pharmacological action

Phenytoin exerts antiseizure activity without causing general depression of the CNS

It is one of the most effective drugs against generalized tonic-clonic seizures and partial seizures

Phenytoin reduces the propagation of abnormal impulses in the brain

Phenytoin prevents the spread of seizures more than that of barbiturates
The drug has membrane stabilizing effects on all neuronal membranes including the peripheral nerve membrane as well as on all non- excitable and excitable membranes

The conversant action produced by drugs like strychnine , picrotixin and pentylenetetrazole are not blocked by phenytoin and the maximal electro shock seizures are effectively controlled by phebytoin

Besides , antiepileptic effects, phenytoin also produces antiarrhythmic effects and is useful in digitalis induced arrhythmias

Pharmacokinetics

Phenytoin is slowly and variably absorbed from the GIT and the peak plasma concentration occurs 3- 12 hrs after ingestion

In plasma it is 70- 95% bound to protein, mainly Albumin

It is metabolized in liver

Phenytoin is enzyme inducer

The inactive metabolite is excreted from the bile, subsequently in urine as a glucronide

Preparation and dose

Phenytoin Sodium I.P

Available as 50 mg and 100 mg Tablets I,V

Preparation containing 50 mg /ml is also available

Normal dose   - 3- 4 mg/kg/day


Adverse effects
Toxicity depends upon  dose , duration and route of administration

Phenytoin inhibits insulin release and produces hyperglycemia

Decreases the release of ADH

Osteomalacia , hypocalcaemia due to altered metabolism of vitamin D and inhibition of intestinal absorption of Ca

Chronic  oral medical effects is dose related and causes change in behavioral effects , increased frequency of seizure , gastric irritation accompanied by nausea and vomiting 

If large amounts are administered intravenously for cardiac arrhythmia or status epileptics  the most important toxic symptoms are cardiovascular collapse or central nervous system depression

Gingival Hyperplasia  -  Hyperpalasia and hypertrophy of the gums with edema and bleeding occur.. It is common in children’s

Hypersensitivity  - Rashes , hepatic necrosis , and neutropenia

Megaloblastic anemia – Phenytoin decreases absorption and increases excretion of folates

Teratogenicity

When taken by the pregnant lady, phenytion produces fetal hydantion syndrome characterized by hypo plastic phalanges, cleft palate,  and harelip

Hirsutism -  Coarsening of facial features ( troublesome in young girls ) , acne


Drug interactions
Phenytoin is an enzyme inducer
Ethanol inactivates phebytoin
Phenytoin given with phenobarbitone , both increases  each other metabolism

Phenytoin and carbamazepine enhance each others metabolism
Valproate displaces protein bound phenytoin

Cimetidine and chloramphenicol  inhibit the metabolism of phenytioin  resulting in toxicity
Antacids decreases the absorption of phenytoin
Sucralfate binds phebytoin in GIT and decreases its  absorption


Therapeutic uses

It is used in all types of epilepsy except petit mal

Phenytoin is highly effective for all partial seizures ( simple and complex), for tonic-chronic seizures and in the treatment of status epileptics
It is specifically useful in grand mal, psychomotor and focal cortical epilepsies

It is also used in cardiac arrhythmias - Dose  - 300 – 400 mg/day

Phenytoin is not effective for absence seizures, which often may worsen if treated with this drug


11. Phenobarbitone

Phenobartitone was the first effective antiepileptic drug to be introduced in 1912. It still remains one of the widely used drugs
It has antiepileptic activity and raises the seizure threshold

Mechanism of action
Barbiturates enhances the inhibitory neurotransmission in the CNS by enhancing the activation of GABA receptors and facilitating the GABA mediated  opening of chloride ion channels

Pharmacokinetics
It is well absorbed orally
The drug freely penetrates  the brain
Approximately 75 % of the drug is inactivated by the hepatic mocrosomal system, whereas the examining drug is excreted unchanged by the kidney
It is a potent inducer of the cytochrome P450 system and when given chronically, it enhances the metabolism of their agents

Dose
60 – 180 mg in divided doses

Adverse effects
Sedation, ataxia, vertigo , nausea and vomiting

Agitation and confusion occur  at high doses
 
Rebound seizures can occur on discontinuance of Phenobarbital

Therapeutic uses
It provides favorable response for simple partial seizures, but it is not very effective for complex partial seizures

The drug had been regarded as the first choice in treating recurrent seizures in children, including febrile seizures

It also used to treat recurrent tonic-clonic seizures, especially in patients who donot respond to diazepam plus phenytoin

It also used as  a mild sedative to relieve anxiety, nervous tension and insomnia

111. Primdone
It structurally related to Phenobarbital and it resembles Phenobarbital in its anticonvulsant activity

It is an  alternative choice in partial seizures and tonic – clonic seizures

It has more efficacy due to the its metabolites Phenobarbital and phenyl-ethyl-malonamide which have longer half- lives than the parent drug

It is effective against tonic-clinic and simple partial seizures and phenyl-ethy-lmalonamide is effective against complex partial seizures

Primidone is often used with carbamazepine and phenytoin

It is well absorbed orally

It exhibits poor protein binding
These drug has the same adverse effects as those seen with Phenobarbital
Dose
500 mg – 5000 mg /day

1V. Carbamaepines

Actions

It reduces the propagation of abnormal impulses in the brain by blocking sodium channels, thereby inhibiting the generation of repetitive action potential in the epileptic focus and preventing their spread

ADME
It is absorbed slowly following oral administration

It enters the brain rapidly because of its high lipid solubility

It induces the drug metabolizing enzymes in the liver

The enhanced hepatic cytochrome p450 system activity also increases the metabolism of many drugs including other antiepileptic drugs

It is an inducer of the cytochromep450  isozyme  cyp3a4, which decrease                                                      the effects of drugs that are metabolized by his enzyme

Adverse effects
Chronic administration of carbamazepine can cause stupor, coma and respiratory depression

It also produces drowsiness, vertigo, ataxia, and blurred vision

The drug is irritating to the stomach and nausea and vomiting may occur

Drug interaction
The hepatic metabolism of carbamazepine is inhibited by several drugs

Toxic symptoms may arise if the dose is not adjusted

Therapeutic uses
It is effective in Temporal lobe epilepsy

Trigeminal neuralgia

Used in post hepatic pain
Dose
It available as 200 mg tab Initial dose 100 mg thrice daily gradually increased to 600 mg – 1200 mg /day

V. Ethosuximide

It reduces propagation of abnormal electrical activity in the brain, most likely by inhibiting t- type calcium channels in a manner similar to the action of phenytoin on sodium channels

It is the first choice in absence seizures

It is well absorbed orally and is not bound to plasma proteins

About 25% of the drug is excreted unchanged in the urine and 75% is converted to inactive metabolites in the liver by the microsomal cytochrome P450 system

It does not induce P450 enzyme synthesis

The drug is irritating to the stomach and nausea and vomiting may occur on chronic  administration

Adverse effects

Drowsiness, lethargy, dizziness , restlessness , agitation , anxiety and the inability to concentrate are often observed

Dose

It is available as 250 mg capsules and as a syrup (250 mg / 5 ml) , initial dose 250 mg, Maximum dose – 750 – 1000 mg


V1. Valproic Acid

It is a broad spectrum anticonvulsant

It has multiple actions , including sodium channel blockade and enhancement of GABAnergic transmission

It is the most effective agent available for treatment of myoclinec seizures

It also diminishes absence seizures, but because of its hepatotixic potential, it is a second choice

It also reduces the incidence and severity of tonic-clonic  seizures

The drug is effective orally and is rapidly absorbed


About 90% is bound to the plasma proteins ,only 3%  of the drug is excreted unchanged, the rest is converted into active metabolites by the liver

It is metabolized by cytochrome P450 enzymes.   Metabolites are excreted by kidney

Adverse effects

It can cause nausea, vomiting ,sedation, ataxia and tremor are common
It inhibits the metabolism of a number of antiepileptic drugs , including Phenobarbital, carbamazepine and ethosuximide

Dose

It is available as capsules containing the equivalent of if 250 mg of valproic acid.

Normally dose 15 mg / kg to be given in divided doses , maximum dose is 60 mg / kg /day


V11. Benzodiazepines

Several of the benzodiazepines show antiepileptic activity

Diazepam and lorazepam are the drugs of choice in the acute treatment  whereas

Clonazepam and clorazepate and clorazepate are used for chronic treatment of status epilepticus

Clonazepam

It suppresses seizure spread from the epileptogenic focus and is effective in absence and myoclonic seizures , but tolerance develops

Clonazepate

Clorazepate is effective in partitial seizures when used in conjunction with other drugs

Diazepam

It is effective against

Pedestal epilepsy

Mylclonic seizures

Status epilepsy

It is drug of choice for status epilepticus

Lorazepam

 Lorazepam and diazepam  are both effective in interrupting the repetitive seizures of status epilepticus.

Lorazepam has a longer duration of action and is preferred by some clinicians

All of the antiepileptics, the benzodiazepines are the safest and most free from severe side effects

All benzodiazepines have sedative properties

Side effects

Drowsiness, Somnolence, Fatigue, Ataxia, Dizziness and behavioral changes Respiratory depression and cardiac depression may occur when given intravenously in acute situations

Anti -   parkinsonism

It was  described b James Parkinson in 1817 and is therefore named after him

Parkinsonism is a chronic , progressive, motor disorder

Characterized by

Akinesia

Muscular rigidity

Tremors

Other symptoms

Excessive salivation

Abnormalities of posture and gait

Seborrhea

Mood changes

The incidence is about 1% of population above 65 years of age

It is usually idiopathic in origin but can also be drug induced

In idiopathic parkinsonism, there is degeneration of nigrostriatal neurons in the basal ganglia resulting in dopamine deficiency

The balance between inhibitory dopaminergic neurons and excitatory cholinergic neurons is disturbed

Antiparkinsonian drugs

It can only help to alleviate the symptoms and improve the quality of life

The two strategies in the treatment are

1. To enhance dopamine activity

2. To depress cholinergic over- activity



Classification of Anti parkinsonism drugs

1. Drugs that increase dopamine levels

A. Dopamine precursor

Levodo[a

B. Drugs that release the dopamine

Amantidine

C. Dopaminergic agonists

Bromocryptine

Lisuride

D. Inhibit dopamine metabolism

MAO inhibitors  -  Selegiline


11. Drug influencing cholinergic system

A. Central anticholinergics

Bintropine

Benzhexol

Biperidine

B. Antihistamines

Diphenhydramine

Promethazine


Etiology and pathogenesis

The causes of neuron degeneration in parkinsonism diseases remain largely unknown

According to oxidative stress theory oxidation of dopamine in the basal ganglia yields highly reactive free radicals that are toxic to dopaminergic neuron and lead to their degeneration

The basal ganglia are a group of interconnected sub cortical nuclei the it include the striatum (caudate and putamen), substantial nigra, globus pallidus and sub thalamus

In healthy individuals, the basal ganglia receive input from the entire cerebral cortex, process this information and send feedback to the motor area of the cortex in a way that leads to the smooth coordination of body movements

Even simple movements such as walking ,involve a complex sequence of motor acts whose smooth execution requires the continuous interplay of the cortex and basal ganglia

In patients with parkinsonism disease , neuron degeneration interrupts this interplay

The basal ganglia function via a series of reciprocal innervations among themselves and the cortex

The striatum receives input from the cerebral cortex and substantial nigra and then sends output to the thalamus via the globus pallidus

The thalamus then feeds information aback to the motor area of the cortex

Two pathways connect the striatum and the thalamus , a direct pathway , which is excitatory and an indirect pathway, which is inhibitory

In patients with parkinsonism disease, t eh degeneration of dopaminergic neuron results in decreased activity in the direct pathway and increased activity in the indirect pathway

As a result, feedback to the cortex is reduced and patients exhibit bradykinesia and rigidity

Excitory cholinergic neurons also participate in the interconnections between structures in the basal ganglia

In parkinsonism disease the degeneration of inhibitory dopaminergic neurons leads to a relative excess of cholinergic activity in these pathways

For this reason, patients with parkinsonism disease can be treated effectively with drugs the inhibit cholinergic activity in the basal ganglia or with drugs that increase dopamine levels and doaminergic activity in the basal ganglia
Levodopa

Acetylcholine and dopamine are excitatory and inhibitory neurotransmitters in the corpus striatum

The dopaminergic system is impaired in parkinsonism, so the balance is disturbed

Levodopa acts by getting converted to dopamine and restoring the balance

Parkinsonism is due to dopamine deficiency

Levodopa improves all the manifestations of parkinsonism

But it is not effective in drug induced parkinsonism

Decarboxylase inhibitors like carbidopa are administered with levodopa

They decrease the peripheral decarboxylation of levodopa

Dopamine is of no therapeutic value because it dies not cross the blood- brain barrier

Levodopa is a prodrug which is converted to dopamine in the body

It crosses the Blood- Brain-Barrier and is taken up by the surviving nigrostriatal neurons


                                  Decarboxylase
Levodopa    -------------------------------------------     Dopamine


Actions

On administration of levodopa, there is an overall improvement in the patient as all the symptoms subside

Other actions

CTZ  -  Dopamine stimulates CTZ to induce vomiting

CVS  -  Large amounts of levodopa converted to dopamine in the periphery causes
             postural hypotension and tachycardia. Dopamine is a catecholamine


Endocrine --  Dopamine suppresses prolactin secretion

Pharmacokinetics

Levodopa is rapidly absorbed from the small intestine

The presence o food delays absorption

Some amino acids in the food compete with levodopa for the absorption and transport to the brain

It undergoes first pass metabolism in the gut and the liver

Its half life is  1-2 hours


Adverse reactions

Large amounts of levodopa is converted to dopamine is the periphery, several adverse effects are expected

Nausea, vomiting, postural hypotension ,palpitation and occasionally arrhythmia can occur

Tolerance develops to these effects after some time

Behavioral effects like anxiety, depression , hallucinations and sometimes psychosis can occur


Use

Levodopa is the most effective drug in idiopathic parkinsonism but is not useful in drug induced parkinsonism


Drug interactions

Pyridoxine enhances peripheral decarboxylation of levodopa and reduces its availability to the CNS

Phenothiazines, metoclopramide and reserine are DA antagonists.

They reverse the effects of levodopa



Carbidopa and benserazide

These Are Peripheral Dopa Decarboxylase Inhibitors

When carbidopa or bensrazide are given with levodopa, they prevent the formation of dopamine in the periphery

They do not cross the BBB and hence allow levodopa to reach the CNS

The combination is synergistic and therefore levodopa is always given with carbidopa or benserazide

Advantages of combination

Dose of levodopa can be reduced by 75%

Response to levodopa appears earlier

Side effects like vomiting and tachycardia are largely reduced

Pyridoxine does not interfere with treatment

Amantadine

It is an antiviral drug

It enhances the release of dopamine in the brain and diminishes the re-uptake of DA

The response starts early and its adverse effects are minor

Large doses produce insomnia, dizziness, vomiting , postural hypotension , hallucinations and ankle edema

Amantadine id used in mild cases of parkinsonism

It can also be used along wit h levodopa as an adjunct

Bromocriptine

It is an ergot derivative having dopamine agonistic activity at D2 receptors

It is used  as
An adjunct to levodopa in the management of on- off phenomenon

An alternative inn patients unable to tolerate levodopa
Adverse effects

It include vomiting , postural hypotension, hallucinations,  skin eruptions and first dose phenomenon   -   sudden cardiovascular collapse
Lisuride and pergolide are similar to bromocriptine

Seleglline

It is a selective MAO- B inhibitor

MAO- B is present in DA containing regions of the CNS

Selegilline prolongs the action of levodopa by preventing its degradation

Selegiline may delay the progression of parkinsonism

Uses  - Mild cases of parkinsonism are started on selegiline. ’It is also used as an adjunct to levodopa

Anti- cholinergic

The cholinergic over activity is overcome by anticholinergics

Tremors, seborrhea and sialorrhiea are reduced more than rigidity

Atropine derivatives like benzhexol,  benztropine, trihexyphenidyl are used

Antihistamines owe their beneficial effects in parkinsonism to their anticholinergic properties

Atropine like side effects such as dry mouth , constipation, blurred vision may be encountered

Uses
Anticholinergics are used as
Adjunct to levodopa
Drugs of choice in drug induced parkinsonism

Drug induced parkinsonism
Drugs like reserpine., metoclopramide and phenothiazines can induce parkinsonism
Reserpine depletes catecholamine stores, metoclopramide and phenothiazines are dopamine antagonists

Treatment withdrawal of the drug usually reverses the symptoms

When drugs are needed, one of the anticholinergics are effective 

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